Title: Boronic Ester Design Enables Rapid, Stereospecific B-Alkyl Suzuki-Miyaura Cross-Coupling Abstract: In the past decades, the Suzuki-Miyaura cross-coupling (SMCC) has been well renowned as the premier method for the facile and selective construction of C(sp2)–C(sp2) bonds. In recent years, B-alkyl SMCC has gained considerable intrigue as a method for creation of C(sp2)–C(sp3) linkages for drug discovery and development. Despite advances made in both ligand and boronate design, these challenging cross-coupling reactions typically suffer from poor yields and long reaction times, stemming f…
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